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How to Remove Black Rust Stains on Wood

When metal and water come into contact with wood, it can leave an ugly black rust stain. Here's how to get rid of it without sanding!

how to remove black stains on wood

We love our butcher block countertops, even though it has its pros and cons. We try to wipe up drips and spills before they stain the surface, and most of the kitchen still looks like new after two years of constant use.

But recently we discovered that a chemical reaction occurs when wet metal touches the wood, like this can of tomatoes left near the sink. Ugh! It was sitting in a puddle of water on the countertop for just a few minutes, but left a black ring on the wood that couldn't be scrubbed away!

Before going through the effort to refinish the entire countertop, I did a little research and found a quick trick to remove the stain that I had to try first! Keep in mind that this will only work on rust from metal, not black stains from mold or other issues. But it's a quick and easy fix that doesn't require any sanding!

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What causes black stains on wood?

These stubborn black stains are caused by a chemical reaction between the metal and the tannins in the wood. Tannins are naturally occurring compounds found in many types of wood, particularly hardwoods like oak, walnut, and maple.

When metal comes into contact with moisture, it can release iron ions. These ions react with the tannins, which appears as a dark or black discoloration on the wood's surface.

black rust stains from brad nails on wooden outdoor planter

I've noticed this reaction happening on some of my outdoor projects that use brad nails, like this plant stand. Now I always build outdoor furniture with galvanized brad nails, which won't cause staining. But I always thought this was a gradual reaction that happens over months or years, not minutes!

How to get rid of black stains on wood

As you can see in the first picture, I had a few of these black circles to fix. Maybe after this, we'll learn not to put cans by the wet sink!

Start by cleaning the area to remove any other dirt or debris from the wood.

black stain on wood countertop

Next, mix oxalic acid (commonly found in cleaners such as Barkeepers Friend) and warm water to form a paste. You may want to wear gloves, eye protection and a mask to protect yourself from the chemicals.

pouring barkeepers friend into a small bowl of water

Apply the mixture to the stain with an old toothbrush. Allow it to sit on the surface of the wood for 15-30 minutes, adding a few drops of water if necessary to prevent it from drying out.

applying oxalic acid to black rust stain on wood countertop

Use a damp paper towel or rag to wipe away the cleaning solution. You can see that most of the black stain was removed with just one application!

wiping off paste to reveal that the black rust stain is gone

There were a couple of stubborn spots from an older stain where you could still see the black line. The surrounding wood was also looking a little dingy. The metal ions must have gotten into the puddle of water and caused a diluted reaction that made it appear gray.

stubborn black stain on wood that requires a second treatment with oxalic acid

I repeated the cleaning process, thickening the mixture slightly and spreading it out further.

applying second treatment of oxalic acid on wood countertop with a toothbrush

I let it sit for a good half hour this time, and it worked like a charm! I applied a quick coat of cutting board oil, and now the countertop by the sink looks brand new!

butcher block countertop with black ring stain removed

This simple trick saved me soooo much time and effort! Instead of sanding and refinishing the entire butcher block countertop, I can just spot clean these stubborn stains as they pop up!

black stain on wood before and after cleaning with oxalic acid